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([ ] refers to molarity) If reaction is in the gas phase, the equilibrium constant is Kp pc pd C D pa pb A B (419)

Figure D-2

where p partial pressure Note that equilibrium constants are dimensional; their units are useful in reconstructing the equilibrium constant expression and the reaction equation on which it is based

aA standard free energy is ( G)0

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field (a search tool) When you do this, you will see the introduction page, and you can begin locating valuable information by clicking on the Class Library hyperlink That link will direct you to a page that has links to every namespace in the NET library, as shown in Figure D-3 TIP You can add the web page to your list of favorites by selecting View | Other Windows and Favorites from the menus If you are anything like us, you will find this page extremely helpful as you become familiar with the classes available to you By selecting one of the namespaces shown in Figure D-3, you will find that you are able to see all of the classes within that namespace There is another way to find help on the NET Class Library, and that is by using Microsoft s MSDN web site at http://msdnmicrosoftcom Currently, the page that you saw in Figure D-2 is also on Microsoft s site (see Figure D-4) Whichever method you choose when accessing the documentation, you will find that Microsoft has spent a fair bit of time in making sure that the information is available to you and is easily readable

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(420)

Figure D-3

where a activity, ( ) refers to molality, and the superscript 0 designates standard state at 25 C (298 K) and unit activity or 1-atm fugacity

Figure D-4

If ( G)0 is negative, the reaction can occur as written (a forward driving force) If ( G)0 is zero, no driving force exists (the system is at equilibrium) If ( G)0 is positive, a reverse reaction can occur (a reverse driving force)

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Microsoft has grouped together a collection of classes that will help you with common tasks Table D-1 gives you an example of some of the classes that you might find in the System namespace Remember that this is just a short list of common classes available in the System namespace Take some time to become familiar with the other classes in the library

Values of ( G)0 are tabulated in many handbooks under the standard free energy change for the reaction (see Refs 2 and 3)

PHASE EQUILIBRIA*

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There are a lot of classes to choose from, but in order to illustrate how to use the class library, we have selected the Math class as our demonstration class Figure D-5 shows the page you will receive if you choose the System link from Figure D-3 and then click the Math link There are a number of things to observe in Figure D-5 Notice that the inheritance hierarchy is in the top left corner the Math class inherits directly from SystemObject In the large, gray-shaded area you can see the definition code for the class public sealed class Math This means that you cannot create any children of the Math class

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